Potassium permanganate

KMnO4KMnO_4

Molar mass: 158.03 g/mol · Class: Strong oxidizing salt

Elements: potassium, manganese, oxygen

Structure

The solid is an ionic lattice of K+ ions and tetrahedral MnO4- ions. In solution the purple permanganate ion oxidizes many substances, itself being reduced to brown manganese dioxide or colorless Mn2+.

Properties

  • Deep purple crystals; intensely purple solutions

  • Strong oxidizing agent

  • Stains skin and fabrics brown

  • Decomposes in light and with organic matter

Applications

  • Water disinfection in wells and aquariums

  • Redox titrations in analytical chemistry

  • Organic synthesis oxidations

Safety note

Strong oxidizer: keep away from flammable materials, glycerin, and concentrated acids; mixtures can ignite. Harmful if swallowed; stains and irritates skin. Store dark, dry, and locked away from children.

Data source: IUPAC standard atomic weights 2021; molar mass computed from KMnO4

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