51SbAntimony

Antimony

Element 51 · Metalloid

Antimony is a brittle, silvery metalloid that sits on the dividing line between metals and nonmetals in group 15. It expands slightly when it solidifies — a rare trait it shares with water and bismuth — which once made antimony-lead alloys ideal for sharp cast type in printing presses. Today its biggest role is invisible: antimony trioxide is the workhorse flame retardant in plastics, textiles, and electronics, slowing the spread of fire. In semiconductors, tiny amounts of antimony tune the electrical properties of silicon, and its compounds appear in infrared detectors and diodes.

Key facts

Atomic number51
Atomic weight121.76
CategoryMetalloid
Group / Period15 / 5
Blockp
Electron configuration[Kr] 4d10 5s2 5p3
Common oxidation states+3, +5, -3
State at STPSolid
Electronegativity2.05
Atomic radius133 pm (empirical)
Density6.697 g/cm³
Melting point630.63 °C
Boiling point1587 °C

Occurrence

Antimony is mined mainly from stibnite (antimony trisulfide), with China producing most of the world's supply. It is a relatively scarce element in Earth's crust.

Applications

  • Flame retardants in plastics and textiles

  • Hardening lead in batteries

  • Semiconductors and infrared detectors

  • Glass clarifying agent

Common compounds

  • Antimony trioxide
  • Stibnite (antimony trisulfide)
  • Antimony pentafluoride
Did you know?

Ancient Egyptians used powdered stibnite — an antimony mineral — as kohl eyeliner more than 5,000 years ago.

Data source: IUPAC standard atomic weights 2021; NIST physical property data

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