9FFluorine

Fluorine

Element 9 · Halogen

Fluorine wants electrons more than any other element, and it takes them by force: it attacks nearly every substance, including some noble gases, and only a few materials survive contact unscathed. That ferocity makes pure fluorine a laboratory challenge handled only by specialists with dedicated equipment. Controlled, though, fluorine is a quiet hero: fluoride ions harden tooth enamel, Teflon (PTFE) coats nonstick pans, and fluorine compounds cool refrigerators and enrich uranium fuel. It never occurs free in nature — every atom on Earth is locked in minerals like fluorite.

Key facts

Atomic number9
Atomic weight19.00
CategoryHalogen
Group / Period17 / 2
Blockp
Electron configuration1s2 2s2 2p5
Common oxidation states-1
State at STPGas
Electronegativity3.98
Atomic radius42 pm
Density0.00170 g/cm³
Melting point-219.67 °C
Boiling point-188.11 °C

Occurrence

Fluorine hides in the minerals fluorite and cryolite and in phosphate rocks. Seawater and most groundwater carry small amounts of dissolved fluoride. It never occurs free in nature.

Applications

  • Fluoride toothpaste and dental treatments

  • Nonstick PTFE (Teflon) coatings

  • Refrigerants and propellants

  • Uranium enrichment (UF6)

  • Hydrofluoric acid for glass etching

Common compounds

  • Hydrogen fluoride (HF)
  • Sodium fluoride (NaF)
  • Calcium fluoride (CaF2)
  • Polytetrafluoroethylene (PTFE)
Did you know?

Fluorine is so aggressive it can set fire to materials — like asbestos and brick — that resist every other chemical.

Data source: IUPAC standard atomic weights 2021

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