3LiLithium

Lithium

Element 3 · Alkali Metal

Lithium is the first alkali metal: a silvery solid so soft it dents under a fingernail and so light it floats on oil. Like all alkali metals it reacts eagerly, tarnishing in air and fizzing in water to release hydrogen, so samples are stored under oil. Lithium's tiny ion slips easily between layers of other materials, which is exactly why lithium-ion batteries dominate phones, laptops, and electric cars. Medicine uses lithium carbonate to stabilize mood in bipolar disorder, and industry turns lithium compounds into heat-resistant glass, lubricating greases, and strong lightweight alloys.

Key facts

Atomic number3
Atomic weight6.94
CategoryAlkali Metal
Group / Period1 / 2
Blocks
Electron configuration1s2 2s1
Common oxidation states+1
State at STPSolid
Electronegativity0.98
Atomic radius167 pm
Density0.534 g/cm³
Melting point180.54 °C
Boiling point1342 °C

Occurrence

Lithium concentrates in salty underground brines beneath salt flats and in the mineral spodumene. The largest reserves sit in South America, Australia, and China. Seawater holds traces, but at concentrations far too low to mine economically.

Applications

  • Lithium-ion rechargeable batteries

  • Mood-stabilizing medication

  • High-temperature lubricating greases

  • Lightweight aluminium alloys for aircraft

  • Specialty glass and ceramics

Common compounds

  • Lithium carbonate (Li2CO3)
  • Lithium hydroxide (LiOH)
  • Lithium chloride (LiCl)
  • Spodumene (LiAlSi2O6)
Did you know?

Lithium is the least dense metal on Earth. It would float on water — if it did not burst into fizzing flame the moment it touched it.

Data source: IUPAC standard atomic weights 2021

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