Moles of Helium in a Balloon (Ideal Gas Law)
A helium party balloon has a volume of 2.00 L at a pressure of 1.00 atm and a temperature of 298 K (25 degC). How many moles of helium are inside, and what is the mass of that helium?
Given
Balloon volume: V = 2.00 L
Pressure: P = 1.00 atm
Temperature: T = 298 K (25 degC + 273.15)
R = 0.08206 L atm / (mol K)
Molar mass of helium: M(He) = 4.0026 g/mol
Find
The amount of helium in moles, and its mass in grams.
Principle
The ideal gas law PV = nRT relates the measurable properties of a gas — pressure, volume, and temperature — to the moles present, using the gas constant R as the bridge. It assumes gas particles are point masses with no attraction, which is a fine approximation for helium at ordinary conditions. Solving for n turns three measurements into a mole count.
Formula
Solution
Write the ideal gas law and solve for n: n = (P x V) / (R x T).
Substitute: n = (1.00 atm x 2.00 L) / (0.08206 L atm mol^-1 K^-1 x 298 K).
Compute the denominator: 0.08206 x 298 = 24.454 L atm mol^-1.
n = 2.00 / 24.454 mol = 0.0818 mol of He.
Convert to mass: m = 0.0818 mol x 4.0026 g/mol = 0.327 g of He.
Unit check
(atm x L) / ((L atm mol^-1 K^-1) x K) simplifies to mol — every unit except moles cancels. Multiplying mol by g/mol leaves grams for the final mass. The unit chain is exact.
What this means physically
A whole party balloon holds less than a tenth of a mole of helium — about a third of a gram, lighter than a paperclip. Gas moles pack loosely: at these conditions each mole fills roughly 24.5 L, which is why balloons are mostly empty space.
Students plug the Celsius temperature (25) directly into PV = nRT, which gives a nonsensical negative-ish mole count. Temperature in every gas-law equation must be absolute (kelvin) — this is the single most common gas-law error.