Identifying the Hydroxyl Group in Ethanol
The compound CH3CH2OH contains an -OH group attached to carbon. Identify the functional group, give the compound's name, and state which family of organic compounds it belongs to.
Given
Molecular structure: CH3CH2OH
The -OH is bonded directly to a carbon atom.
Find
The functional group present, the compound's name, and its organic family.
Principle
A functional group is an atom or group of atoms that gives a molecule its characteristic chemistry. An -OH group bonded to a carbon atom is the hydroxyl group, and any molecule containing it belongs to the alcohol family. Alcohols are named from the longest carbon chain with the suffix -ol.
Formula
Solution
Locate the characteristic group: the -OH attached to the CH2 carbon is the hydroxyl functional group.
A molecule with a hydroxyl group bonded to carbon belongs to the alcohol family.
Count the longest carbon chain: 2 carbons → root 'eth-' with the alcohol suffix '-ol' → ethanol.
Confirm: CH3CH2OH is the two-carbon alcohol, commonly known as ethanol.
Unit check
Functional-group identification is qualitative, so no units apply; the structural check is that the formula CH3CH2OH contains exactly one -OH on a two-carbon chain, matching the name ethanol.
What this means physically
The hydroxyl group defines the alcohols, a family whose hydrogen bonding gives them much higher boiling points than similar-size alkanes — ethanol boils at 78 C while ethane boils at -89 C. Recognizing -OH on sight is the first step in predicting an organic molecule's behavior.
Students often confuse the -OH of an alcohol with the hydroxide ion OH-. In ethanol the OH is covalently bonded to carbon as a neutral functional group; hydroxide is a free ion with a negative charge — very different species.