Percent Yield

Percent yield = (actual yield ÷ theoretical yield) × 100%: the fraction of the predicted product a reaction really delivers.

What it means

The theoretical yield is what perfect stoichiometry promises from the limiting reactant; the actual yield is what you really weigh at the end. Their ratio, expressed as a percent, grades the reaction's efficiency. Anything below 100% reflects the real world: side reactions, incomplete conversion, and product left behind on glassware and filter paper.

Variables

SymbolNameUnitMeaning
actualyieldactual yieldActual yieldg or molThe mass or moles of product genuinely obtained and isolated from the reaction.
theoreticalyieldtheoretical yieldTheoretical yieldg or molThe maximum mass or moles of product the stoichiometry predicts from the limiting reactant.
% yieldPercent yield%The efficiency of the reaction as a percentage; always 100% or less for a clean experiment.

Assumptions

  • Both yields are expressed in the same units — grams with grams, moles with moles.
  • The theoretical yield comes from the limiting-reactant stoichiometry.
  • A result above 100% signals measurement error or an impure, contaminated product.
  • The actual yield is the mass or moles genuinely isolated, not estimated.

Worked example

Problem

A synthesis has a theoretical yield of 25.0 g, but only 18.4 g of pure product is isolated. Calculate the percent yield.

Given:

  • Theoretical yield = 25.0 g
  • Actual yield = 18.4 g
  1. Write % yield = (actual yield / theoretical yield) × 100%.

  2. Substitute: % yield = (18.4 g / 25.0 g) × 100%.

  3. Divide: 18.4 / 25.0 = 0.736.

  4. Multiply by 100%: 0.736 × 100% = 73.6%.

73.6%

The reaction delivered about three-quarters of the stoichiometric promise — respectable, with the missing 26.4% lost to side reactions and handling.